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Accessibility information
Author(s):   Viola, A.; MacMillan, J.H.; Proverb, R.J.; Yates, B.L.
Title:   Participation of acetylenic bonds in pericyclic reactions. Thermal cleavage of β-hydroxyacetylenes
Journal:   J. Am. Chem. Soc.
Volume:   93
Page(s):   6967 - 6974
Year:   1971
Reference type:   Journal article
Squib:   1971VIO/MAC6967-6974

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1971VIO/MAC6967-6974   HC≡CCH2C(CH3)2OH → Acetone + CH2=C=CH2  561 - 648   3.98E11       1.67E05      1
  1971VIO/MAC6967-6974   HC≡CCH2CH2OHCH2O + CH2=C=CH2  571 - 643   1.58E11       1.67E05      1
  1971VIO/MAC6967-6974   3-Hexyn-1-olCH2O + CH2=C=CHCH2CH3  563 - 643   1.58E11       1.75E05      1
  1971VIO/MAC6967-6974   CH3CH(OH)CH2C≡CHCH3CHO + CH2=C=CH2  564 - 643   2.00E11       1.65E05      1
  1971VIO/MAC6967-6974   C6H5C≡CCH2CH2OH → CH2O + Benzene, 1,2-propadienyl-  608 - 693   3.16E11       341      1
  1971VIO/MAC6967-6974   3-Octyn-1-olCH2O + CH2=C=CHCH2CH2CH2CH3  598 - 683   5.01E10       1.69E05      1
  1971VIO/MAC6967-6974   HC≡CCH2CH(OH)CH2CH3C2H5CHO + CH2=C=CH2  598 - 643   1.26E12       1.71E05      1
  1971VIO/MAC6967-6974   HC≡CC(CH3)2C(CH3)2OH → Acetone + CH2=C=C(CH3)2  563 - 643   2.51E12       1.70E05      1

Search returned 8 records.