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Author(s):   Viola, A.; MacMillan, J.H.; Proverb, R.J.; Yates, B.L.
Title:   Participation of acetylenic bonds in pericyclic reactions. Thermal cleavage of β-hydroxyacetylenes
Journal:   J. Am. Chem. Soc.
Volume:   93
Page(s):   6967 - 6974
Year:   1971
Reference type:   Journal article
Squib:   1971VIO/MAC6967-6974

Reaction:   HC≡CCH2CH2OHCH2O + CH2=C=CH2
Reaction order:   1
Temperature:   571 - 643 K
Rate expression:   1.58x1011 [s-1] e-167121 [J/mole]/RT
Bath gas:   HC≡CCH2CH2OH
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
571 8.14E-5
575 1.04E-4
600 4.46E-4
625 1.71E-3
643 4.20E-3