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Title: Rotating sector study of the gas phase photolysis of the carbon tetrachloride-cyclohexane system
Journal: Int. J. Chem. Kinet.
Volume: 3
Page(s): 127 - 136
Year: 1971
Reference type: Journal article
Squib: 1971WHI/KUN127-136
Reaction:
Cyclohexane + ·CCl3 → CHCl3 + Cyclohexyl
Reaction order:
2
Reference reaction:
·CCl3 + ·CCl3 → CCl3CCl3
Temperature:
385 - 456
K
Rate expression:
1.02x10-12 [cm3/molecule s] e-44732 [J/mole]/RT
Bath gas:
CCl4
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 385 | 8.74E-19 |
| 400 | 1.48E-18 |
| 425 | 3.26E-18 |
| 450 | 6.58E-18 |
| 456 | 7.70E-18 |