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Accessibility information
Author(s):   Yates, B.L.; Ramirez, A.; Velasquez, O.
Title:   The thermal decomposition of β-hydroxy esters
Journal:   J. Org. Chem.
Volume:   36
Year:   1971
Reference type:   Journal article
Squib:   1971YAT/RAM3579

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1971YAT/RAM3579   CH3CH(OH)CH2C(O)OC2H5CH3CHO + CH3C(O)OC2H5  583 - 613   9.55E10       1.66E05      1
  1971YAT/RAM3579   C6H5CH(OH)CH2C(O)OC2H5Benzaldehyde + CH3C(O)OC2H5  523 - 553   3.72E11       1.60E05      1
  1971YAT/RAM3579   (CH3)2C(OH)CH2C(O)OCH3Acetone + CH3C(O)OCH3  563 - 593   2.19E11       1.64E05      1
  1971YAT/RAM3579   (CH3)2C(OH)CH2C(O)OC2H5Acetone + CH3C(O)OC2H5  563 - 593   1.58E11       1.61E05      1
  1971YAT/RAM3579   CH3CH(OH)CH(CH3)C(O)OC2H5CH3CHO + C2H5C(O)OC2H5  573 - 603   1.78E11       1.63E05      1

Search returned 5 records.