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Accessibility information
Author(s):   Baldwin, R.R.; Jackson, D.; Melvin, A.; Rossiter, B.N.
Title:   The Second Limit of Hydrogen + Carbon Monoxide + Oxygen Mixtures
Journal:   Int. J. Chem. Kinet.
Volume:   4
Year:   1972
Reference type:   Journal article
Squib:   1972BAL/JAC277

Reaction:   CO + CO2
Reaction order:   3
Temperature:   300 - 3500 K
Rate expression:   8.27x10-34 [cm6/molecule2 s] e-12555 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
300 5.39E-36
400 1.90E-35
500 4.04E-35
600 6.68E-35
700 9.57E-35
800 1.25E-34
900 1.55E-34
1000 1.83E-34
1100 2.10E-34
1200 2.35E-34
1300 2.59E-34
1400 2.81E-34
1500 3.02E-34
1600 3.22E-34
1700 3.40E-34
1800 3.58E-34
1900 3.74E-34
2000 3.89E-34
2100 4.03E-34
2200 4.16E-34
2300 4.29E-34
2400 4.41E-34
2500 4.52E-34
2600 4.63E-34
2700 4.73E-34
2800 4.82E-34
2900 4.91E-34
3000 5.00E-34
3100 5.08E-34
3200 5.16E-34
3300 5.23E-34
3400 5.31E-34
3500 5.37E-34