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Accessibility information
Author(s):   Bertrand, L.; Bizongwako, J.; Huybrechts, G.; Olbregts, J.
Title:   Oxygen-inhibited photochlorination of 1,2-dichloroethane
Journal:   Bull. Soc. Chim. Belg.
Volume:   81
Page(s):   73 - 80
Year:   1972
Reference type:   Journal article
Squib:   1972BER/BIZ73-80

Reaction:   Cl2 + CH2ClCHCl· → CHCl2CH2Cl + Cl
Reaction order:   2
Reference reaction:   O2 + CH2ClCHCl· → CH2ClCHClO2
Reference reaction order:   2
Temperature:   298 - 328 K
Pressure:  0.11 - 0.37 bar
Rate expression:   3.16x101 e-8398 [±8314472 J/mole]/RT
Uncertainty:   5.0
Bath gas:   Cl2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.07E0
300 1.09E0
325 1.41E0
328 1.45E0