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Author(s):
Bertrand, L.; Bizongwako, J.; Huybrechts, G.; Olbregts, J.
Title:
Oxygen-inhibited photochlorination of 1,2-dichloroethane
Journal:
Bull. Soc. Chim. Belg.
Volume:
81
Page(s):
73 - 80
Year:
1972
Reference type:
Journal article
Squib:
1972BER/BIZ73-80
Reaction:
Cl2 + CH2ClCHCl· → CHCl2CH2Cl + Cl
Reaction order:
2
Reference reaction:
O2 + CH2ClCHCl· → CH2ClCHClO2
Reference reaction order:
2
Temperature:
298 - 328
K
Pressure: 0.11 - 0.37 bar
Rate expression:
3.16x101 e-8398 [±8314472 J/mole]/RT
Uncertainty:
5.0
Bath gas:
Cl2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
T (K) | k(T) [] |
298 |
1.07E0 |
300 |
1.09E0 |
325 |
1.41E0 |
328 |
1.45E0 |
|