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Title: Oxygen-inhibited photochlorination of 1,2-dichloroethane
Journal: Bull. Soc. Chim. Belg.
Volume: 81
Page(s): 73 - 80
Year: 1972
Reference type: Journal article
Squib: 1972BER/BIZ73-80
Reaction:
Cl2 + CH2ClCHCl· → CHCl2CH2Cl + ·Cl
Reaction order:
2
Reference reaction:
O2 + CH2ClCHCl· → CH2ClCHClO2
Reference reaction order:
2
Temperature:
298 - 328
K
Pressure: 0.11 - 0.37 bar
Rate expression:
3.16x101 e-8398 [±8314472 J/mole]/RT
Uncertainty:
5.0
Bath gas:
Cl2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 298 | 1.07E0 |
| 300 | 1.09E0 |
| 325 | 1.41E0 |
| 328 | 1.45E0 |