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Accessibility information
Author(s):   Ferguson, K.C.; Whittle, E.
Title:   Kinetics of the reaction between HBr and CF3Br. Determination of the bond dissociation energy D(CF3-Br)
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972FER/WHI295

Reaction:   ·CF3 + Br2CF3Br + Br·
Reaction order:   2
Reference reaction:   ·CF3 + HBrCHF3 + Br·
Reference reaction order:   2
Temperature:   320 - 769 K
Pressure:  0.70 - 0.92 bar
Rate expression:   5.61 e-7824 [±392 J/mole]/RT
Uncertainty:   1.09000003
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
320 2.96E-1
325 3.10E-1
350 3.81E-1
375 4.56E-1
400 5.34E-1
425 6.13E-1
450 6.93E-1
475 7.74E-1
500 8.54E-1
525 9.34E-1
550 1.01E0
575 1.09E0
600 1.17E0
625 1.24E0
650 1.32E0
675 1.39E0
700 1.46E0
725 1.53E0
750 1.60E0
769 1.65E0