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Author(s):   Foon, R.; Reid, G.P.; Tait, K.B.
Title:   Kinetic hydrogen isotope effect in the fluorination of H2, CH4 and CHCl3
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972FOO/REI1131

Reaction:   CH2Cl2 + ·FCHCl2 + HF
Reaction order:   2
Reference reaction:   CHCl3 + ·F·CCl3 + HF
Reference reaction order:   2
Temperature:   296 - 326 K
Rate expression:   1.44±2.4x10-1 e2087 [±8314472 J/mole]/RT
Bath gas:   H2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
296 3.36E0
300 3.32E0
325 3.12E0
326 3.11E0