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Accessibility information
Author(s):   Foon, R.; Tait, K.B.
Title:   Chlorine abstraction reactions of fluorine. Part 3.-Thermochemical data for chlorofluoroalkanes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Page(s):  
Year:   1972
Reference type:   Journal article
Squib:   1972FOO/TAI1121

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1972FOO/TAI1121   CCl4 + ·F·CCl3 + ClF  450 - 470   1.66E-11       4.27E04      2
  1972FOO/TAI1121   CFCl3 + ·F → Products  589 - 733   0.20       -2.08E04      2
  Reference reaction:  CFCl2CFCl2 + ·F → Products 2
  1972FOO/TAI1121   CFCl3 + ·F·CCl2F + ClF  520 - 540   5.25E-12       5.48E04      2
  1972FOO/TAI1121   CF2Cl2 + ·F → Products  596 - 747   1.09       -6394      2
  Reference reaction:  CF2Cl-CF2Cl + ·F → Products 2
  1972FOO/TAI1121   CF2Cl2 + ·F → Products  665 - 790   2.63       -6693      2
  Reference reaction:  CF3CF2Cl + ·F → Products 2
  1972FOO/TAI1121   CF2Cl2 + ·F·CClF2 + ClF  664 - 684   2.62E-11       6.98E04      2
  1972FOO/TAI1121   CF3Cl + ·F·CF3 + ClF  755 - 775   1.05E-10       8.73E04      2
  1972FOO/TAI1121   CF2Cl-CF2Cl + ·FClF + CCl2F2CF2  663 - 683   2.62E-11       7.62E04      2
  1972FOO/TAI1121   CF3CF2Cl + ·FC2F5 + ClF  725 - 745   1.05E-11       7.70E04      2

Search returned 9 records.