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Accessibility information
Author(s):   Foon, R.; Tait, K.B.
Title:   Chlorine abstraction reactions of fluorine. Part 3.-Thermochemical data for chlorofluoroalkanes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Page(s):  
Year:   1972
Reference type:   Journal article
Squib:   1972FOO/TAI1121

Reaction:   CFCl3 + ·F → Products
Reaction order:   2
Reference reaction:   CFCl2CFCl2 + ·F → Products
Reference reaction order:   2
Temperature:   589 - 733 K
Pressure:  1.87E-2 - 7.07E-2 bar
Rate expression:   2.0x10-1 e20786 [±8314472 J/mole]/RT
Uncertainty:   1.32000005
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
589 1.39E1
600 1.29E1
625 1.09E1
650 9.36E0
675 8.12E0
700 7.11E0
725 6.29E0
733 6.06E0