Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Foon, R.; Tait, K.B.
Title:   Chlorine abstraction reactions of fluorine. Part 3.-Thermochemical data for chlorofluoroalkanes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972FOO/TAI1121

Reaction:   CFCl3 + ·F → Products
Reaction order:   2
Reference reaction:   CFCl2CFCl2 + ·F → Products
Reference reaction order:   2
Temperature:   589 - 733 K
Pressure:  1.87E-2 - 7.07E-2 bar
Rate expression:   2.0x10-1 e20786 [±8314472 J/mole]/RT
Uncertainty:   1.32000005
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
589 1.39E1
600 1.29E1
625 1.09E1
650 9.36E0
675 8.12E0
700 7.11E0
725 6.29E0
733 6.06E0