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Accessibility information
Author(s):   Maloney, K.L.; Palmer, H.B.; Seery, D.J.
Title:   The rate of dissociation of allyl iodide in shock waves
Journal:   Int. J. Chem. Kinet.
Volume:   4
Page(s):   87 - 102
Year:   1972
Reference type:   Journal article
Squib:   1972MAL/PAL87-102

Reaction:   CH2CHCH2I·CH2CH=CH2 + I
Reaction order:   1
Temperature:   742 - 1070 K
Pressure:  0.23 - 1.91 bar
Rate expression:   2.82x1014 [s-1] e-178761 [±10726 J/mole]/RT
Uncertainty:   2.50999999
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
742 7.35E1
750 1.00E2
775 2.52E2
800 6.01E2
825 1.36E3
850 2.92E3
875 6.01E3
900 1.19E4
925 2.27E4
950 4.18E4
975 7.47E4
1000 1.30E5
1025 2.19E5
1050 3.61E5
1070 5.29E5