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Author(s):   McMillen, D.F.; Golden, D.M.; Benson, S.W.
Title:   The rate of the gas phase iodination of cyclobutane. The heat of formation of the cyclobutyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   4
Page(s):   487 - 495
Year:   1972
Reference type:   Journal article
Squib:   1972MCM/GOL487-495

Reaction:   Cyclobutane + ICyclobutyl + HI
Reaction order:   2
Temperature:   589 - 662 K
Pressure:  1.47E-2 - 0.23 bar
Rate expression:   7.59x10-10 [cm3/molecule s] e-112245 [±1122 J/mole]/RT
Uncertainty:   1.28999996
Bath gas:   Cyclobutane
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
589 8.43E-20
600 1.28E-19
625 3.16E-19
650 7.25E-19
662 1.06E-18