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Accessibility information
Author(s):   Oele, P.C.; Tinkelenberg, A.; Louw, R.
Title:   Thermolysis of Alkyl Thiol- and Thionoacetates
Journal:   Tetrahedron Lett.
Year:   1972
Reference type:   Journal article
Squib:   1972OEL/TIN2375

Reaction:   CH3C(S)OCH2CH3C2H4 + CH3COSH
Reaction order:   1
Temperature:   763 - 841 K
Rate expression:   3.16x1012 [s-1] e-172110 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
763 5.22E0
775 7.94E0
800 1.83E1
825 4.01E1
841 6.46E1