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Accessibility information
Author(s):   Quick, L.M.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with organic halides. Part 7.-Chloro- and fluorochloro-ethanes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972QUI/WHI878

Reaction:   CH3CCl3 + ·CF3CHF3 + CCl3CH2
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3C2F6
Temperature:   339 - 478 K
Pressure:  4.80E-2 - 7.07E-2 bar
Rate expression:   4.17x10-14 [cm3/molecule s] e-30098 [±3916 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
339 9.60E-19
350 1.34E-18
375 2.68E-18
400 4.89E-18
425 8.33E-18
450 1.34E-17
475 2.04E-17
478 2.14E-17