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Accessibility information
Author(s):   Rozenberg, A.S.; Voronkov, V.G.
Title:   Rate constants for the interaction of the NH biradical and the aminoradical with alkane molecules
Journal:   Russ. J. Phys. Chem. (Engl. Transl.)
Volume:   46
Year:   1972
Reference type:   Journal article
Squib:   1972ROZ/VOR425

Reaction:   CH4 + NH2·CH3 + NH3
Reaction order:   2
Reference reaction:   HN3 + NH2NH3 + ·N3
Reference reaction order:   2
Temperature:   880 - 3230 K
Rate expression:   8.59x10-1±4.5x10-1 e-7533 [±4598 J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
880 3.07E-1
900 3.14E-1
1000 3.47E-1
1100 3.77E-1
1200 4.04E-1
1300 4.28E-1
1400 4.50E-1
1500 4.70E-1
1600 4.88E-1
1700 5.04E-1
1800 5.19E-1
1900 5.33E-1
2000 5.46E-1
2100 5.58E-1
2200 5.69E-1
2300 5.79E-1
2400 5.89E-1
2500 5.98E-1
2600 6.06E-1
2700 6.14E-1
2800 6.22E-1
2900 6.29E-1
3000 6.35E-1
3100 6.41E-1
3200 6.47E-1
3230 6.49E-1