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Accessibility information
Author(s):   Sarner, S.F.; Gale, D.M.; Hall, H.K., Jr.; Richmond, A.B.
Title:   Gas-Phase Thermolysis Kinetics of Small Ring Nitriles
Journal:   J. Phys. Chem.
Volume:   76
Page(s):  
Year:   1972
Reference type:   Journal article
Squib:   1972SAR/GAL2817

Reaction:   1,2-Cyclobutanedicarbonitrile, trans- → CH2CHCN + CH2CHCN
Reaction order:   1
Temperature:   593 - 683 K
Rate expression:   2.51x1012 [s-1] e-172110 [J/mole]/RT
Bath gas:   1,2-Cyclobutanedicarbonitrile, trans-
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
593 1.74E-3
600 2.61E-3
625 1.04E-2
650 3.71E-2
675 1.21E-1
683 1.73E-1