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Accessibility information
Author(s):   Simonaitis, R.; Heicklen, J.
Title:   Kinetics and Mechanism of the Reaction of O(3P) with Carbon Monoxide
Journal:   J. Chem. Phys.
Volume:   56
Page(s):   2004 - 2011
Year:   1972
Reference type:   Journal article
Squib:   1972SIM/HEI2004-2011

Reaction:   CO + CO2
Reaction order:   2
Temperature:   298 - 472 K
Pressure:  0.29 - 1.09 bar
Rate expression:   2.66x10-14 [cm3/molecule s] e-12139 [J/mole]/RT
Bath gas:   N2O
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Sensitized photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.98E-16
300 2.05E-16
325 2.97E-16
350 4.10E-16
375 5.41E-16
400 6.91E-16
425 8.56E-16
450 1.04E-15
472 1.21E-15