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Accessibility information
Author(s):   Wilson, W.E., Jr.
Title:   A critical review of the gas-phase reaction kinetics of the hydroxyl radical
Journal:   J. Phys. Chem. Ref. Data
Volume:   1
Page(s):   535 - 573
Year:   1972
Reference type:   Journal article
Squib:   1972WIL535-573

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1972WIL535-573   CH2O + ·OHHCO + H2O  700 - 1600   8.30E-09       5.40E04      2
  1972WIL535-573   CH4 + ·OH·CH3 + H2O  300 - 2000   4.73E-11       2.08E04      2
  1972WIL535-573   CH4 + ·OH·CH3 + H2O  300 - 2000   92.00       -1.83E04      2
  Reference reaction:  CO + ·OHCO2 + 2
  1972WIL535-573   CH3Br + ·OHH2O + ·CH2Br  1780 - 1820   2.49E-11              2
  1972WIL535-573   C2H6 + ·OH·C2H5 + H2O  300 - 2000   1.08E-10       1.50E04      2
  1972WIL535-573   C2H4 + ·OH → Products  300 - 2000   4.98E-12              2
  1972WIL535-573   C2H2 + ·OH → Products  1000 - 1600   9.96E-12       2.91E04      2
  1972WIL535-573   C2H2 + ·OH → Products  300 - 1000   1.99E-13              2
  1972WIL535-573   CH3Cl + ·OH·CH2Cl + H2O  1850 - 2100   2.16E-11              2
  1972WIL535-573   CO + ·OHCO2 +   300 - 2000   5.15E-13       2494      2
  1972WIL535-573   H2 + ·OHH2O +   300 - 2000   3.82E-11       2.16E04      2
  1972WIL535-573   H2 + ·OHH2O +   300 - 2000   72.90       -1.91E04      2
  Reference reaction:  CO + ·OHCO2 + 2
  1972WIL535-573   ·CH3 + ·OH → Products  1970 - 2190   6.64E-12              2
  1972WIL535-573   ·OH + ·OHH2O2  500 - 1000   2.31E-33       2.20E04      3
  1972WIL535-573   ·OH + ·OHH2O +   300   2.57E-12              2
  1972WIL535-573   ·OH + HClH2O + ·Cl  1920 - 1940   1.33E-11              2
  1972WIL535-573   ·OH + HNO3H2O + NO3  300   1.66E-13              2
  1972WIL535-573   ·OH + H2O2HO2 + H2O  300 - 1000   1.66E-11       1.50E04      2
  1972WIL535-573   ·OH + HBrH2O + Br·  1880 - 2000   2.66E-24              2
  1972WIL535-573   ·OH + C2CO + ·CH  2200   8.30E-12              2
  1972WIL535-573   ·OH + H2 +   500 - 3000   2.24E-11       3.33E04      2
  1972WIL535-573   ·OH + H2O  1000 - 3300   7.64E-31   -2.60          3
  1972WIL535-573   ·OH + H2O  1000 - 3300   1.52E-29   -2.60          3
  1972WIL535-573   ·OH + SOSO2 +   300   1.16E-10              2
  1972WIL535-573   ·OH + HNO → Products  1600 - 2000   1.66E-10              2
  1972WIL535-573   ·OH + O2 +   300 - 2000   4.15E-11              2
  1972WIL535-573   ·OH + NNO +   320   5.81E-11              2
  1972WIL535-573   NH3 + OD → Products  500   1.66E-13              2

Search returned 28 records.