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Title: Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 69
Page(s):
Year: 1973
Reference type: Journal article
Squib: 1973ARI/POT1811
Reaction:
n-C4H10 + ·CF3 → CHF3 + sec-C4H9
Reaction order:
2
Reference reaction:
n-C4H10 + ·CF3 → CHF3 + n-C4H9
Reference reaction order:
2
Temperature:
314 - 443
K
Pressure: 5.71E-2 - 0.16 bar
Rate expression:
4.1x10-1 e11058 [±881 J/mole]/RT
Uncertainty:
1.23000002
Bath gas:
CF3I
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 314 | 2.83E1 |
| 325 | 2.45E1 |
| 350 | 1.83E1 |
| 375 | 1.42E1 |
| 400 | 1.14E1 |
| 425 | 9.37E0 |
| 443 | 8.25E0 |