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Accessibility information
Author(s):   Arican, M.H.; Potter, E.; Whytock, D.A.
Title:   Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Year:   1973
Reference type:   Journal article
Squib:   1973ARI/POT1811

Reaction:   n-C4H10 + ·CF3CHF3 + sec-C4H9
Reaction order:   2
Reference reaction:   n-C4H10 + ·CF3CHF3 + n-C4H9
Reference reaction order:   2
Temperature:   314 - 443 K
Pressure:  5.71E-2 - 0.16 bar
Rate expression:   4.1x10-1 e11058 [±881 J/mole]/RT
Uncertainty:   1.23000002
Bath gas:   CF3I
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
314 2.83E1
325 2.45E1
350 1.83E1
375 1.42E1
400 1.14E1
425 9.37E0
443 8.25E0