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Accessibility information
Author(s):   Berkley, R.E.; Safarik, I.; Gunning, H.E.; Strausz, O.P.
Title:   Arrhenius parameters for the reactions of methyl radicals with silane and methylsilanes
Journal:   J. Phys. Chem.
Volume:   77
Page(s):  
Year:   1973
Reference type:   Journal article
Squib:   1973BER/SAF1734

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1973BER/SAF1734   (CH3)4Si + ·CH3CH4 + (CH3)3SiCH2  331 - 487   3.64E-13       4.04E04      2
  1973BER/SAF1734   neo-C5H12 + ·CH3CH4 + Neopentyl  365 - 495   1.38E-12       4.91E04      2
  1973BER/SAF1734   CH3SiH3 + ·CH3CH4 + CH3SiH2  373   37.00              2
  Reference reaction:  CH3SiD3 + ·CH3 → Other Products + CH3D 2
  1973BER/SAF1734   CH3SiH3 + ·CH3CH4 + CH3SiH2  298 - 424   3.17E-12       3.40E04   3.47E-18  2
  1973BER/SAF1734   (CH3)3SiH + ·CH3CH4 + (CH3)3Si·  302 - 486   8.14E-13       3.48E04      2
  1973BER/SAF1734   (CH3)3SiH + ·CH3CH4 + (CH3)3Si·  373   2.80              2
  Reference reaction:  ·CH3 + (CH3)3SiD → CH3D + (CH3)3Si· 2
  1973BER/SAF1734   (CH3)2SiD2 + CD3 → Other Products + CD4  295 - 425   1.38E-12       3.69E04   4.67E-19  2
  1973BER/SAF1734   CH3SiD3 + CD3 → Other Products + CD4  295 - 425   5.13E-12       3.85E04   9.18E-19  2
  1973BER/SAF1734   CH3SiD3 + ·CH3 → Other Products + CH3D  297 - 474   2.96E-12       3.86E04   5.11E-19  2
  1973BER/SAF1734   (CH3)2SiH2 + ·CH3CH4 + (CH3)2SiH  373   2.90              2
  Reference reaction:  (CH3)2SiD2 + ·CH3 → Other Products + CH3D 2
  1973BER/SAF1734   (CH3)2SiH2 + ·CH3CH4 + (CH3)2SiH  300 - 485   1.96E-12       3.48E04      2
  1973BER/SAF1734   CD3 + (CH3)3SiD → CD4 + (CH3)3Si·  299 - 489   1.59E-13       3.79E04      2

Search returned 12 records.