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Author(s):   Cadman, P.; Tilsley, G.M.; Trotman-Dickenson, A.F.
Title:   Abstraction of chlorine atoms from alkyl chlorides by the trimethylsilyl radical
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Page(s):   914 - 921
Year:   1973
Reference type:   Journal article
Squib:   1973CAD/TIL914-921

Reaction:   tert-C4H9Cl + (CH3)3Si·(CH3)3SiCl + tert-C4H9
Reaction order:   2
Reference reaction:   (CH3)3Si· + (CH3)3Si·(CH3)6Si2
Temperature:   400 - 580 K
Rate expression:   2.34x10-13 [cm3/molecule s] e-12389 [J/mole]/RT
Bath gas:   H2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
400 5.65E-15
425 7.03E-15
450 8.54E-15
475 1.02E-14
500 1.19E-14
525 1.37E-14
550 1.56E-14
575 1.75E-14
580 1.79E-14