Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Davis, D.D.; Payne, W.A.; Stief, L.J.
Title:   The Hydroperoxyl Radical in Atmospheric Chemical Dynamics: Reaction with Carbon Monoxide
Journal:   Science
Volume:   179
Year:   1973
Reference type:   Journal article
Squib:   1973DAV/PAY280

Reaction:   CO + HO2CO2 + ·OH
Reaction order:   2
Temperature:   300 K
Pressure:  2.67E-2 - 0.27 bar
Rate expression:   1.0x10-20 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.