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Accessibility information
Author(s):   Encina, M.V.; Lissi, E.A.
Title:   Reaction of Acetyl Radicals with Buta-1,3-diene
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Year:   1973
Reference type:   Journal article
Squib:   1973ENC/LIS1505

Reaction:   1,3-Butadiene + CH3CO → Products
Reaction order:   2
Reference reaction:   CH3COCO + ·CH3
Reference reaction order:   1
Temperature:   333 - 397 K
Pressure:  0.27 bar
Rate expression:   2.49x10-24 [cm3/molecule] e43900 [±4390 J/mole]/RT
Uncertainty:   5.0
Bath gas:   C3H8
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule]
333 1.92E-17
350 8.87E-18
375 3.24E-18
397 1.49E-18