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Accessibility information
Author(s):   Kwart, H.; Sarner, S.F.; Slutsky, J.
Title:   Mechanisms of thermolytic fragmentation of allyl ethers. I.
Journal:   J. Am. Chem. Soc.
Volume:   96
Page(s):  
Year:   1973
Reference type:   Journal article
Squib:   1973KWA/SAR5234

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1973KWA/SAR5234   CH3CH2OCH2CH=CH2CH3CHO + CH3CH=CH2  725 - 792   1.82E11       1.74E05      1
  1973KWA/SAR5234   (CH2=CHCH2)2OCH2=CHCHO + CH3CH=CH2  672 - 755   4.07E11       1.71E05      1
  1973KWA/SAR5234   CH2=CHCH2OCH3CH2O + CH3CH=CH2  725 - 810   1.23E11       1.74E05      1
  1973KWA/SAR5234   (CH3)3COCH2CH=CH2Acetone + 1-C4H8  792 - 850   3.39E13       2.29E05      1
  1973KWA/SAR5234   C6H5CH2OCH2C≡CH → Benzaldehyde + CH2=C=CH2  675 - 763   8.32E11       1.71E05      1
  1973KWA/SAR5234   C6H5CH2OCH2C(CH3)=CH2Benzaldehyde + iso-C4H8  714 - 776   2.69E11       1.71E05      1
  1973KWA/SAR5234   (CH3)2CHOCH2CH=CH2Acetone + CH3CH=CH2  710 - 792   2.19E11       1.73E05      1
  1973KWA/SAR5234   C6H5CH2OCH2CH=CH2Benzaldehyde + CH3CH=CH2  695 - 778   3.39E11       1.72E05      1
  1973KWA/SAR5234   CH3OCH(C6H5)CH=CH2CH2O + 3-Phenylpropene  718 - 789   1.62E12       1.82E05      1
  1973KWA/SAR5234   Benzene, 1,3,5-trimethyl-2-((2-propenyloxy)methyl)- → CH3CH=CH2 + Benzaldehyde, 2,4,6-trimethyl-  735 - 786   9.12E11       1.86E04      1
  1973KWA/SAR5234   Benzene, 2-(1-methoxy-2-propenyl)-1,3,5-trimehyl- → CH2O + Benzene, 1,3,5-trimethyl-2-(2-propenyl)-  697 - 759   1.45E12       1.81E06      1

Search returned 11 records.