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Author(s):   Kwart, H.; Slutsky, J.; Sarner, S.F.
Title:   The kinetic deuterium isotope criterion applied to th thermolysis of alkyl allyl ethers. II
Journal:   J. Am. Chem. Soc.
Volume:   95
Page(s):   5242 - 5245
Year:   1973
Reference type:   Journal article
Squib:   1973KWA/SLU5242-5245

Reaction:   (CH3)2CHOCH2CH=CH2Acetone + CH3CH=CH2
Reaction order:   1
Reference reaction:   (CD3)2CDOCH2CH=CH2(CD3)2CO + CH2=CHCH2D
Reference reaction order:   1
Temperature:   710 - 797 K
Pressure:  1.01 bar
Rate expression:   6.0x10-1 e5438 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
710 1.51E0
725 1.48E0
750 1.44E0
775 1.40E0
797 1.36E0