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Accessibility information
Author(s):   Rodgers, A.S.; Ford, W.G.F.
Title:   Analysis of the kinetics of the thermal and chemically activated elimination of HF from 1,1,1-trifluoroethane: the C-C bond dissociation energy and the heat of formation of 1,1,1-trifluoroethane
Journal:   Int. J. Chem. Kinet.
Volume:   5
Page(s):   965 - 975
Year:   1973
Reference type:   Journal article
Squib:   1973ROD/FOR965-975

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Temperature:   1000 - 1800 K
Rate expression:   3.98x1014 [s-1] e-303478 [J/mole]/RT
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 5.60E-2
1050 3.18E-1
1100 1.55E0
1150 6.54E0
1200 2.46E1
1250 8.29E1
1300 2.55E2
1350 7.21E2
1400 1.89E3
1450 4.65E3
1500 1.08E4
1550 2.36E4
1600 4.93E4
1650 9.83E4
1700 1.89E5
1750 3.48E5
1800 6.21E5