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Accessibility information
Author(s):   Watkins, K.W.; Thompson, W.W.
Title:   Addition of Ethyl Radicals to Carbon Monoxide. Kinetic and Thermochemical Properties of the Propionyl Radical
Journal:   Int. J. Chem. Kinet.
Volume:   5
Year:   1973
Reference type:   Journal article
Squib:   1973WAT/THO791

Reaction:   CH3CH2COCO + ·C2H5
Reaction order:   1
Temperature:   238 - 278 K
Pressure:  1.33E-2 - 0.35 bar
Rate expression:   5.89x1012 [s-1] e-60280 [J/mole]/RT
Bath gas:   CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
238 3.47E-1
250 1.50E0
275 2.09E1
278 2.78E1