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Author(s):   Wu, E-Chung; Rodgers, A.S.
Title:   The gas-phase kinetics of the reaction of 1,1,1-trifluoroethyl iodine with HI: The C-I bond dissocation energy in 2,2,2-trifluoroethyl iodide
Journal:   Int. J. Chem. Kinet.
Volume:   5
Page(s):  
Year:   1973
Reference type:   Journal article
Squib:   1973WU/ROD1001

Reaction:   CF3CH2I + ICF3CH2 + I2
Reaction order:   2
Temperature:   525 - 602 K
Pressure:  1.60E-2 - 4.67E-2 bar
Rate expression:   5.25x10-10 [cm3/molecule s] e-83145 [±831 J/mole]/RT
Uncertainty:   1.25999999
Bath gas:   CF3CH2I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
525 2.80E-18
550 6.66E-18
575 1.47E-17
600 3.03E-17
602 3.20E-17