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Author(s):   Atkinson, R.; Pitts, J.N., Jr.
Title:   Rate Constants for the Reaction of O(3P) Atoms with SO2(M = N2O) over the Temperature Range 299-392K
Journal:   Chem. Phys. Lett.
Volume:   29
Year:   1974
Reference type:   Journal article
Squib:   1974ATK/PIT28

Reaction:   SO2 + SO3
Reaction order:   3
Temperature:   299 - 392 K
Pressure:  7.20E-2 - 0.18 bar
Rate expression:   9.15x10-32 [cm6/molecule2 s] e-8398 [±1671 J/mole]/RT
Bath gas:   N2O
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Sensitized photolysis
Analytical technique:   Vis-UV emission

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
299 3.12E-33
300 3.16E-33
325 4.09E-33
350 5.11E-33
375 6.19E-33
392 6.96E-33