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Author(s):   Bakh, G.; Novak, Z.; Korochuk, S.I.; Kalinenko, R.A.
Title:   The Role of Hydrogen Atoms and Methyl Radicals in the Pyrolysis of Mixtures of Alkane and Alkene Hydrocarbons
Journal:   Kinet. Catal.
Volume:   15
Year:   1974
Reference type:   Journal article
Squib:   1974BAK/NOV1103

Reaction:   n-C4H10 → Products
Reaction order:   1
Temperature:   973 - 1120 K
Pressure:  6.67E-2 - 0.13 bar
Rate expression:   1.5x1012 [s-1] e-222828 [±6677 J/mole]/RT
Bath gas:   n-C4H10
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
973 1.64E0
975 1.73E0
1000 3.44E0
1025 6.62E0
1050 1.23E1
1075 2.23E1
1100 3.94E1
1120 6.08E1