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Accessibility information
Author(s):   Bauer, S.H.; Yadava, B.P.; Jeffers, P.
Title:   Relative Cis-Trans Isomerization Rates. Another Test of the Energy Randomization Hypothesis
Journal:   J. Phys. Chem.
Volume:   78
Page(s):  
Year:   1974
Reference type:   Journal article
Squib:   1974BAU/YAD770

Reaction:   (Z)-2-C6H12(E)-2-C6H12
Reaction order:   1
Reference reaction:   (Z)-2-C4H8(E)-2-C4H8
Temperature:   1000 - 1150 K
Pressure:  0.24 - 0.40 bar
Rate expression:   3.98x1014 [s-1] e-276872 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 1.37E0
1025 3.09E0
1050 6.71E0
1075 1.40E1
1100 2.84E1
1125 5.56E1
1150 1.06E2