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Accessibility information
Author(s):   Beadle, P.C.; Knox, J.H.
Title:   Activated chloroalkyl radicals in the chlorination of olefins
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   72
Page(s):   1418 - 1433
Year:   1974
Reference type:   Journal article
Squib:   1974BEA/KNO1418-1433

Reaction:   C2Cl5C2Cl4 + ·Cl
Reaction order:   1
Reference reaction:   C2Cl5 + Cl2CCl3CCl3 + ·Cl
Temperature:   300 - 350 K
Pressure:  0.27 bar
Rate expression:   2.95x1013 [s-1] e-64853 [±8314472 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   SF6
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.51E2
325 1.11E3
350 6.18E3