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Author(s):   Case, R.S.; Dewar, M.J.S.; Kirschner, St.; Petit, R.; Slegeir, W.
Title:   Possible intervention of triplet states in thermal reactions of hydrocarbons. A study of the rearrangements of cyclobutadiene dimers and analogous compounds
Journal:   J. Am. Chem. Soc.
Volume:   96
Year:   1974
Reference type:   Journal article
Squib:   1974CAS/DEW7581

Reaction:   Tricyclo[,5]octa-3,7-diene,(1α,2β,5β,6α)-1,3,5,7-Cyclooctatetraene
Reaction order:   1
Temperature:   365 - 375 K
Rate expression:   1.51x1014 [s-1] e-135526 [±4066 J/mole]/RT
Uncertainty:   5.0
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
365 6.09E-6
375 2.00E-5