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Author(s):   Davis, D.D.; Fischer, S.; Schiff, R.
Title:   Flash Photolysis-Resonance Fluorescence Kinetics Study: Temperature Dependence of the Reactions OH + CO →’ CO2 + H and OH + CH4 →’ H2O + CH3
Journal:   J. Chem. Phys.
Volume:   61
Year:   1974
Reference type:   Journal article
Squib:   1974DAV/FIS2213

Reaction:   CO + ·OHCO2 +
Reaction order:   2
Temperature:   220 - 373 K
Pressure:  2.67E-2 - 0.13 bar
Rate expression:   2.14x10-13 [±1.99x10-14 cm3/molecule s] e-673 [±337 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 1.48E-13
225 1.49E-13
250 1.55E-13
275 1.60E-13
300 1.64E-13
325 1.67E-13
350 1.70E-13
373 1.72E-13