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Author(s):   Golden, D.M.; Alfassi, Z.B.; Beadle, P.C.
Title:   Very Low-Pressure Pyrolysis (VLPP) of Alkanes: n-Butane, 2,3-Dimethylbutane, 2,2',3,3'-Tetramethylbutane, and Isobutane
Journal:   Int. J. Chem. Kinet.
Volume:   6
Year:   1974
Reference type:   Journal article
Squib:   1974GOL/ALF359

Reaction:   n-C4H10·C2H5 + ·C2H5
Reaction order:   1
Temperature:   1100 - 1250 K
Rate expression:   2.51x1016 [s-1] e-338399 [J/mole]/RT
Bath gas:   n-C4H10
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 2.14E0
1125 4.87E0
1150 1.07E1
1175 2.27E1
1200 4.68E1
1225 9.34E1
1250 1.82E2