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Accessibility information
Author(s):   Hautecloque, S.
Title:   No. 3. - Reactions des radicaux trichloromethyle avec des bromomethanes et deuteriobromomethanes. Effet isotopique primaire
Journal:   J. Chim. Phys. Phys. Chim. Biol.
Volume:   71
Year:   1974
Reference type:   Journal article
Squib:   1974HAU13

Reaction:   CH4 + ·CCl3CHCl3 + ·CH3
Reaction order:   2
Reference reaction:   CD4 + ·CCl3 → CCl3D + CD3
Reference reaction order:   2
Temperature:   488 - 573 K
Rate expression:   1.26x101 e-5853 [J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
488 2.98E0
500 3.08E0
525 3.30E0
550 3.50E0
573 3.69E0