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Accessibility information
Author(s):   Hautecloque, S.
Title:   No. 3. - Reactions des radicaux trichloromethyle avec des bromomethanes et deuteriobromomethanes. Effet isotopique primaire
Journal:   J. Chim. Phys. Phys. Chim. Biol.
Volume:   71
Year:   1974
Reference type:   Journal article
Squib:   1974HAU13

Reaction:   CHBr3 + ·CCl3CHCl3 + CBr3
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   488 - 573 K
Rate expression:   8.3x10-9 [cm3/molecule s] e-88965 [±8314472 J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
488 2.49E-18
500 4.22E-18
525 1.17E-17
550 2.95E-17
573 6.45E-17