Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Scherzer, K.; Drechsler, M.
Title:   Reaction of Methyl Radicals with 2-Butanone-1,1,1,3,3-d5 and the Stability of the Butanonyl Radicals
Journal:   React. Kinet. Catal. Lett.
Volume:   1
Year:   1974
Reference type:   Journal article
Squib:   1974SCH/DRE79

Reaction:   (CH3N)2 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   ·CH3 + CD3C(O)CD2CH3 → Other Products + CH3D
Reference reaction order:   2
Temperature:   523 - 563 K
Pressure:  5.33E-2 - 8.00E-2 bar
Rate expression:   6.31x10-1 e4814 [±1688 J/mole]/RT
Uncertainty:   1.25999999
Bath gas:   CD3C(O)CD2CH3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
523 1.91E0
525 1.90E0
550 1.81E0
563 1.76E0