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Author(s):   Whytock, D.A.; Clark, J.D.; Gray, P.
Title:   Reaction of perfluoroethyl radicals with cycloalkanes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   70
Year:   1974
Reference type:   Journal article
Squib:   1974WHY/CLA411

Reaction:   Cycloheptane + C2F5C2F5H + Cycloheptyl
Reaction order:   2
Reference reaction:   C2F5 + C2F5n-C4F10
Temperature:   301 - 428 K
Pressure:  3.80E-2 - 9.00E-2 bar
Rate expression:   1.83x10-12 [cm3/molecule s] e-99774 [±3002 J/mole]/RT
Uncertainty:   1.23000002
Bath gas:   C2F5I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
301 8.86E-30
325 1.68E-28
350 2.35E-27
375 2.31E-26
400 1.71E-25
425 9.98E-25
428 1.22E-24