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Accessibility information
Author(s):   Abuin, E.; Lissi, E.A.
Title:   Arrhenius Parameters for the Photocleavage of Butan-2-one Triplets
Journal:   J. Photochem.
Volume:   5
Year:   1975
Reference type:   Journal article
Squib:   1975ABU/LIS65

Reaction:   C2H5COCH3·C2H5 + CH3CO
Reaction order:   1
Temperature:   291 - 346 K
Pressure:  0.53 bar
Rate expression:   4.27x1014 [s-1] e-105594 [±17959 J/mole]/RT
Bath gas:   C3H8
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
291 4.75E-5
300 1.76E-4
325 4.57E-3
346 4.89E-2