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Author(s):   Colussi, A.J.; Singleton, D.L.; Irwin, R.S.; Cvetanovic, R.J.
Title:   Absolute rates of oxygen(3P) atoms reactions with benzene and toluene
Journal:   J. Phys. Chem.
Volume:   79
Year:   1975
Reference type:   Journal article
Squib:   1975COL/SIN1900

Reaction:   Toluene + → Products
Reaction order:   2
Temperature:   298 - 462 K
Pressure:  5.33E-2 - 0.11 bar
Rate expression:   3.82x10-11 [±1.99x10-12 cm3/molecule s] e-16130 [±161 J/mole]/RT
Bath gas:   N2O
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Sensitized photolysis
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 5.68E-14
300 5.94E-14
325 9.76E-14
350 1.50E-13
375 2.16E-13
400 2.99E-13
425 3.98E-13
450 5.12E-13
462 5.73E-13