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Accessibility information
Author(s):   Ernst, J.; Spindler, K.
Title:   Untersuchungen zum Thermischen Zerfall von Acetaldehyd und Aceton
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   79
Year:   1975
Reference type:   Journal article
Squib:   1975ERN/SPI1163

Reaction:   Acetone·CH3 + CH3CO
Reaction order:   1
Temperature:   1400 - 1600 K
Pressure:  0.22 - 73.99 bar
Rate expression:   2.0x1016 [s-1] e-338399 [±13553 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 4.74E3
1425 7.89E3
1450 1.29E4
1475 2.08E4
1500 3.29E4
1525 5.13E4
1550 7.89E4
1575 1.20E5
1600 1.79E5