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Accessibility information
Author(s):   Gaffney, J.S.; Atkinson, R.; Pitts, J.N., Jr.
Title:   Temperature Dependence of the Relative Rate Constants for the Reaction of O(3P) Atoms with Selected Olefins, Monoterpenes, and Unsaturated Aldehydes
Journal:   J. Am. Chem. Soc.
Volume:   97
Page(s):  
Year:   1975
Reference type:   Journal article
Squib:   1975GAF/ATK6481

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1975GAF/ATK6481   alpha-pinene + → Products  296 - 423   1.25E-10       3808   2.68E-11  2
  1975GAF/ATK6481   alpha-pinene + → Products  296 - 423   13.50       5604   1.41  2
  Reference reaction:  Cyclopentene + → Products 2
  1975GAF/ATK6481   CH2=CHCHO + → Products  296 - 423   2.32E-11       1.01E04   4.01E-13  2
  1975GAF/ATK6481   CH2=CHCHO + → Products  296 - 423   2.46       1.18E04   0.02  2
  Reference reaction:  Cyclopentene + → Products 2
  1975GAF/ATK6481   beta-pinene + → Products  296 - 423   9.96E-11       3434   2.49E-11  2
  1975GAF/ATK6481   beta-pinene + → Products  296 - 423   10.80       5147   1.35  2
  Reference reaction:  Cyclopentene + → Products 2
  1975GAF/ATK6481   Cyclopentene + → Products  296 - 423   9.30E-12       -1796   1.92E-11  2
  1975GAF/ATK6481   Cyclohexene, 1-methyl- + → Products  296 - 423   8.80E-12       -5562   8.31E-11  2
  1975GAF/ATK6481   Cyclohexene, 1-methyl- + → Products  296 - 423   0.95       -3766   4.35  2
  Reference reaction:  Cyclopentene + → Products 2
  1975GAF/ATK6481   1,3-Cyclohexadiene + → Products  296 - 423   8.49E-12       -5521   7.88E-11  2
  1975GAF/ATK6481   1,3-Cyclohexadiene + → Products  296 - 423   0.92       -3725   4.14  2
  Reference reaction:  Cyclopentene + → Products 2
  1975GAF/ATK6481   (E)-CH3CH=CHCHO + → Products  296 - 423   2.49E-11       8281   8.81E-13  2
  1975GAF/ATK6481   (E)-CH3CH=CHCHO + → Products  296 - 423   2.62       1.01E04   0.05  2
  Reference reaction:  Cyclopentene + → Products 2
  1975GAF/ATK6481   d-Limonene + → Products  296 - 423   1.83E-10       1255   1.10E-10  2
  1975GAF/ATK6481   d-Limonene + → Products  296 - 423   19.60       3010   5.82  2
  Reference reaction:  Cyclopentene + → Products 2

Search returned 15 records.