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Author(s):   Gaffney, J.S.; Atkinson, R.; Pitts, J.N., Jr.
Title:   Temperature Dependence of the Relative Rate Constants for the Reaction of O(3P) Atoms with Selected Olefins, Monoterpenes, and Unsaturated Aldehydes
Journal:   J. Am. Chem. Soc.
Volume:   97
Year:   1975
Reference type:   Journal article
Squib:   1975GAF/ATK6481

Reaction:   d-Limonene + → Products
Reaction order:   2
Reference reaction:   Cyclopentene + → Products
Temperature:   296 - 423 K
Pressure:  0.27 - 0.67 bar
Rate expression:   1.83x10-10 [cm3/molecule s] e-1255 [±628 J/mole]/RT
Bath gas:   N2O
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Sensitized photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 1.10E-10
300 1.10E-10
325 1.15E-10
350 1.19E-10
375 1.22E-10
400 1.25E-10
423 1.28E-10