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Author(s):   Gaffney, J.S.; Atkinson, R.; Pitts, J.N., Jr.
Title:   Temperature Dependence of the Relative Rate Constants for the Reaction of O(3P) Atoms with Selected Olefins, Monoterpenes, and Unsaturated Aldehydes
Journal:   J. Am. Chem. Soc.
Volume:   97
Year:   1975
Reference type:   Journal article
Squib:   1975GAF/ATK6481

Reaction:   d-Limonene + → Products
Reaction order:   2
Reference reaction:   Cyclopentene + → Products
Reference reaction order:   2
Temperature:   296 - 423 K
Pressure:  0.27 - 0.67 bar
Rate expression:   1.96x101 e-3010 [±301 J/mole]/RT
Bath gas:   N2O
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Sensitized photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
296 5.77E0
300 5.86E0
325 6.43E0
350 6.97E0
375 7.46E0
400 7.93E0
423 8.33E0