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Author(s):   Knoll, H.; Wilhelm, H.-D.; Scherzer, K.
Title:   Uber den thermischen zerfall von acetonylaceton
Journal:   Z. Phys. Chem. (Leipzig)
Volume:   256
Year:   1975
Reference type:   Journal article
Squib:   1975KNO/WIL673

Reaction:   2,5-Hexanedione + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   2,5-Hexanedione + ·CH3(CH3)2CO + C2H5COCH3
Reference reaction order:   2
Temperature:   515 - 712 K
Pressure:  0.31 - 0.86 bar
Rate expression:   1.0 e13553 [±136 J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
515 2.37E1
525 2.23E1
550 1.94E1
575 1.70E1
600 1.51E1
625 1.36E1
650 1.23E1
675 1.12E1
700 1.03E1
712 9.87E0