Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Luu, S.H.; Glanzer, K.; Troe, J.
Title:   Thermal Isomerization in Shock Waves and Flash Photolysis of Cycloheptatriene, III
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   79
Year:   1975
Reference type:   Journal article
Squib:   1975LUU/GLA855

Reaction:   1,3,5-CycloheptatrieneToluene
Reaction order:   1
Temperature:   600 - 1300 K
Pressure:  0.27 - 2.31 bar
Rate expression:   6.31x1013 [s-1] e-217839 [J/mole]/RT
Uncertainty:   1.12
Bath gas:   Ar
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
600 6.85E-6
650 1.97E-4
700 3.51E-3
750 4.25E-2
800 3.77E-1
850 2.59E0
900 1.44E1
950 6.65E1
1000 2.64E2
1050 9.19E2
1100 2.86E3
1150 8.05E3
1200 2.08E4
1250 4.98E4
1300 1.12E5