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Author(s):   Luu, S.H.; Glanzer, K.; Troe, J.
Title:   Thermal Isomerization in Shock Waves and Flash Photolysis of Cycloheptatriene, III
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   79
Year:   1975
Reference type:   Journal article
Squib:   1975LUU/GLA855

Reaction:   1,3,5-CycloheptatrieneToluene
Reaction order:   1
Temperature:   900 - 1300 K
Pressure:  0.27 - 2.31 bar
Rate expression:   3.16x1013 [s-1] e-208693 [±6269 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 2.44E1
925 5.19E1
950 1.06E2
975 2.09E2
1000 3.97E2
1025 7.32E2
1050 1.31E3
1075 2.29E3
1100 3.89E3
1125 6.46E3
1150 1.05E4
1175 1.67E4
1200 2.60E4
1225 3.99E4
1250 6.01E4
1275 8.91E4
1300 1.30E5