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Author(s):   Manning, R.G.; Grant, E.R.; Merrill, J.C.; Parks, N.J.; Root, J.W.
Title:   Hydrogen abstraction by fluorine atoms under conditions of thermal initiation: Hydrocarbons and fluorinated hydrocarbons
Journal:   Int. J. Chem. Kinet.
Volume:   7
Page(s):  
Year:   1975
Reference type:   Journal article
Squib:   1975MAN/GRA39

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1975MAN/GRA39   CH4 + ·F·CH3 + HF  303   2.58              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   C2H6 + ·F·C2H5 + HF  303   7.40              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   CH2F2 + ·F·CHF2 + HF  303   0.28              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   Cyclopropane + ·FCyclopropyl + HF  303   8.26              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   CHF3 + ·F·CF3 + HF  303   0.03              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   Cyclohexane + ·FCyclohexyl + HF  303   11.00              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   Cyclopentane + ·FCyclopentyl + HF  303   23.40              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   CH3CF3 + ·FCF3CH2 + HF  303   0.10              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   neo-C5H12 + ·FNeopentyl + HF  303   14.00              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   CD4 + ·FCD3 + DF  303   1.66              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   CH3F + ·F·CH2F + HF  3000   1.49              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   (CD3)4C + ·FDF + (CD3)3CCD2  303   948              2
  Reference reaction:  H2 + ·FHF + 2
  1975MAN/GRA39   D2 + ·FDF + D  303   0.52              2
  Reference reaction:  H2 + ·FHF + 2

Search returned 13 records.