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Accessibility information
Author(s):   Taylor, R.
Title:   The Nature of the Transition State in Ester Pyrolysis. Part II. The Relative Rates of Pyrolysis of Ethyl, Isopropyl, and t-Butyl Acetates,Phenylacetates, Benzoates, Phenyl Carbonates, and N-Phenylcarbamates
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):   1025 - 1029
Year:   1975
Reference type:   Journal article
Squib:   1975TAY1025-1029

Reaction:   Carbamic acid, phenyl-, 1,1-dimethylethyl esteraniline + iso-C4H8 + CO2
Reaction order:   1
Temperature:   521 - 596 K
Pressure:  2.00E-2 - 0.20 bar
Rate expression:   6.31x1013 [s-1] e-167121 [±3342 J/mole]/RT
Uncertainty:   1.58000004
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
521 1.11E-3
525 1.49E-3
550 8.48E-3
575 4.16E-2
596 1.42E-1